
Olivia lee
Leave a messageNames and Identifiers | |
Name | Lithium borohydride |
Lithium borohydride | |
lithium boron(-1) anion | |
Lithium tetrahydroborate | |
Lithium boron tetrahydride | |
Lithium borohydride (LBH) | |
Lithium Borohydride in THF | |
Borate(1-), tetrahydro-, lithium | |
LithiuM borohydride, 2.0 M solution in THF | |
Lithium borohydride [UN1413] [Dangerous when wet] | |
CAS | 16949-15-8 |
EINECS | 241-021-7 |
Chemical structure | |
Physico-chemical Properties | |
Molecular Formula | BH4Li |
Molar Mass | 21.78 |
Density | 0.896g/mLat 25°C |
Melting Point | 280 °C |
Boling Point | 66°C/760mmHg |
Flash Point | −1°F |
Water Solubility | soluble H2O above pH 7, ether, tetrahydrofuran, aliphatic amines [MER06] |
Solubility | Soluble in ether, THF, and aliphatic aminesSoluble in ether, tetrahydrofuran, aliphatic amines and ethanol. |
Appearance | Powder |
Specific Gravity | 0.66 |
Color | White |
Odor | |
Exposure Limit | 4.00-75.60%(V) |
Storage Condition | water-free area |
Stability | |
Sensitive | Air & Moisture Sensitive |
Dangerous Cargo Mark | |
Risk and Safety | |
Risk Codes | R14/15 -Reacts violently with water, liberating highly Flammable gases. |
R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. | |
R34 - Causes burns | |
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. | |
R11 - Highly Flammable | |
R40 - Limited evidence of a carcinogenic effect | |
R36/37/38 - Irritating to eyes, respiratory system and skin. | |
R19 - May form explosive peroxides | |
R67 - Vapors may cause drowsiness and dizziness | |
R66 - Repeated exposure may cause skin dryness or cracking | |
R22 - Harmful if swallowed | |
R12 - Extremely Flammable | |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. | |
S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.) | |
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) | |
S36/37 - Wear suitable protective clothing and gloves. | |
S16 - Keep away from sources of ignition. | |
UN IDs | UN 3399 4.3/PG 1 |
WGK Germany | 2 |
RTECS | ED2725000 |
TSCA | YES |
HS Code | 2850 00 20 |
Hazard Class | 4.3 |
Packing Group | 1 |
Toxicity | |
Category | flammable articles in contact with water |
flammability hazard characteristics | flammable when exposed to water; flammable hydrogen when exposed to water |
storage and transportation characteristics | warehouse ventilation and low temperature drying; separate from hydrochloric acid |
fire extinguishing agent | dry powder, dry sand |
Use | Commonly used as raw materials for the preparation of other borohydrides. Used as a reducing agent for hydrogen sources and organic groups (such as aldehydes, ketones, esters). It is industrially used for bleaching wood pulp and electroless plating (electroless plating). Used as a Strong reducing agent, it can reduce aldehydes, ketones and esters. |
Strong reducibility
Lithium borohydride is a strong reducing agent, superior to Sodium borohydride and potassium, and is often used in selective Reduction reactions in Organic synthesis, such as aldehydes, ketones, carboxylic acids, nitriles, etc., and in the preparation of other borohydrides. In chemical reactions, lithium borohydride can provide electron pairs, reduce a variety of organic functional groups (such as carbonyl, nitrile, etc.), and convert them into more saturated structures such as corresponding alcohols and amines, showing its strong reducing ability.
The strong reductivity of lithium borohydride stems from the chemical structure, in which the boron atom forms a tetrahedron with four hydrogen atoms, with the lithium atom at the center. This structure gives it strong reductive properties that allow it to react with other substances to reduce its oxidation state. Compared with other compounds (such as sodium borohydride), lithium borohydride has a good solubility in inert solvents, especially in organic solvents. A higher solubility means that a higher effective concentration can be achieved in the reaction medium, thereby improving the speed and efficiency of the reduction reaction.
Copyright © 2006-2022 Gansu Junmao New Materials Technology Co., Ltd. All Rights Reserved. SITEMAP