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    Lithium borohydride

    Lithium borohydride (LiBH4) appears as a colorless powder at room temperature and pressure, insoluble in hydrocarbons, benzene, ether, but soluble in liquid ammonia. It will decompose under heating conditions, and the aqueous solution is easy to hydrolyze and react quickly with acid. As a hydrogen production raw material and organic synthetic reducing agent, lithium borohydride can be prepared by the reaction of sodium borohydride and lithium chloride.
  • Category:
    Borohydride
  • Browse number:
    172
  • Release time:
    2024-08-22 13:50:49
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Names and Identifiers
NameLithium borohydride

Lithium borohydride
lithium boron(-1) anion
Lithium tetrahydroborate
Lithium boron tetrahydride
Lithium borohydride (LBH)
Lithium Borohydride in THF
Borate(1-), tetrahydro-, lithium
LithiuM borohydride, 2.0 M solution in THF
Lithium borohydride [UN1413] [Dangerous when wet]
CAS16949-15-8
EINECS241-021-7
Chemical structure
Physico-chemical Properties
Molecular FormulaBH4Li
Molar Mass21.78
Density0.896g/mLat 25°C
Melting Point280 °C
Boling Point66°C/760mmHg
Flash Point−1°F
Water Solubilitysoluble H2O above pH 7, ether, tetrahydrofuran, aliphatic amines [MER06]
SolubilitySoluble in ether, THF, and aliphatic aminesSoluble in ether, tetrahydrofuran, aliphatic amines and ethanol.
AppearancePowder
Specific Gravity0.66
ColorWhite
Odor
Exposure Limit4.00-75.60%(V)
Storage Conditionwater-free area
Stability
SensitiveAir & Moisture Sensitive
Dangerous Cargo Mark



Risk and Safety
Risk CodesR14/15 -Reacts violently with water, liberating highly Flammable gases.
R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed.
R34 - Causes burns
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R11 - Highly Flammable
R40 - Limited evidence of a carcinogenic effect
R36/37/38 - Irritating to eyes, respiratory system and skin.
R19 - May form explosive peroxides
R67 - Vapors may cause drowsiness and dizziness
R66 - Repeated exposure may cause skin dryness or cracking
R22 - Harmful if swallowed
R12 - Extremely Flammable
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37 - Wear suitable protective clothing and gloves.
S16 - Keep away from sources of ignition.
UN IDsUN 3399 4.3/PG 1
WGK Germany2
RTECSED2725000
TSCAYES
HS Code2850 00 20
Hazard Class4.3
Packing Group1
Toxicity
Categoryflammable articles in contact with water
flammability hazard characteristicsflammable when exposed to water; flammable hydrogen when exposed to water
storage and transportation characteristicswarehouse ventilation and low temperature drying; separate from hydrochloric acid
fire extinguishing agentdry powder, dry sand
UseCommonly used as raw materials for the preparation of other borohydrides. Used as a reducing agent for hydrogen sources and organic groups (such as aldehydes, ketones, esters). It is industrially used for bleaching wood pulp and electroless plating (electroless plating).
Used as a Strong reducing agent, it can reduce aldehydes, ketones and esters.


Strong reducibility

Lithium borohydride is a strong reducing agent, superior to Sodium borohydride and potassium, and is often used in selective Reduction reactions in Organic synthesis, such as aldehydes, ketones, carboxylic acids, nitriles, etc., and in the preparation of other borohydrides. In chemical reactions, lithium borohydride can provide electron pairs, reduce a variety of organic functional groups (such as carbonyl, nitrile, etc.), and convert them into more saturated structures such as corresponding alcohols and amines, showing its strong reducing ability.

The strong reductivity of lithium borohydride stems from the chemical structure, in which the boron atom forms a tetrahedron with four hydrogen atoms, with the lithium atom at the center. This structure gives it strong reductive properties that allow it to react with other substances to reduce its oxidation state. Compared with other compounds (such as sodium borohydride), lithium borohydride has a good solubility in inert solvents, especially in organic solvents. A higher solubility means that a higher effective concentration can be achieved in the reaction medium, thereby improving the speed and efficiency of the reduction reaction.



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