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    Sodium aluminum hydride

    Sodium aluminum hydride, also known as sodium tetrahydroaluminate with the formula NaAlH4, is a white crystalline chemical. Under certain conditions, it has unique chemical properties. When heated to 180 ° C, sodium aluminum hydride will undergo a decomposition reaction, releasing a lot of energy. With a relative density of 1.2, it can remain stable in dry air and is not easily affected by the environment. However, sodium aluminum hydride is extremely sensitive to moisture and proton-containing solvents. Therefore, special moisture-proof measures need to be taken during storage and use. Typically, in laboratory or industrial Settings, sodium aluminum hydride will be stored in well-sealed containers and placed in a dry, cool place.
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    hydride
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    222
  • Release time:
    2024-08-22 14:07:34
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Product information
Names and Identifiers
NameSodium aluminium hydride
SynonymsSodium aluminium hydride
Sodium aluminum hydride hydrogen-storage grade
SodiuM aluMiniuM hydride, 2.0 M solution in THF, HySeal
SodiuM aluMiniuM hydride, 1.0 M solution in THF, HySeal
CAS13770-96-2
EINECS237-400-1
Chemical structure
Physico-chemical Properties
Molecular FormulaNa.AlH4
Molar Mass54
Density0.905g/mLat 25°C
Melting Point178 °C
Flash Point-10 °C
Storage Conditionwater-free area
Risk and Safety
Risk CodesR14/15 -Reacts violently with water, liberating highly Flammable gases.
R22 - Harmful if swallowed
R34 - Causes burns
R19 - May form explosive peroxides
R15 - Contact with water liberates extremely flammable gases
R11 - Highly Flammable
R40 - Limited evidence of a carcinogenic effect
R36/37/38 - Irritating to eyes, respiratory system and skin.
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S7/8 -Keep container tightly closed and dry.
S33 - Take precautionary measures against static discharges.
S16 - Keep away from sources of ignition.
S36/37 - Wear suitable protective clothing and gloves.
UN IDsUN 2835 4.3/PG 2
German Water Endangerment Class1
Registry of Toxic Effects of Chemical SubstancesBD0180000
HS Code28500090
Hazard Class4.3
USEsodium aluminum hydride is used as a hydrogen (or thermal) storage system. They have the advantages of large storage capacity and low cost.
categorywater burning articles
toxicity gradepoisoning
Acute toxicityoral-mouse LD50: 740 mg/kg
explosive hazard characteristicsexplosion of hydrogen emitted by water and moist air
flammability hazard characteristicswhen water or moist air emits hydrogen
storage and transportation characteristicsThe warehouse is ventilated and dried at low temperature; It is stored separately from oxidant, halogen and strong acid
extinguishing agentdry powder, dry sand, dry powder
Occupational StandardTWA 2 mg (AL) /m3



Sodium aluminum hydride, chemical formula NaAlH4, is a typical aluminum hydride with significant activity and reaction rates. In view of its structural characteristics, safety must be strictly guaranteed during storage and transportation, and contact with air, water, etc., to prevent the risk of violent reactions.

In the field of scientific research, sodium aluminum hydride has attracted much attention because of its unique chemical properties. Its high Hydrogen storage density makes it an ideal hydrogen storage material. When hydrogen is needed to be released, sodium aluminum hydride can be hydrolyzed or pyrolyzed under specific conditions to release a large amount of hydrogen, thus showing a broad application prospect in the field of hydrogen energy.


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