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Names and Identifiers | |
Name | Sodium aluminium hydride |
Synonyms | Sodium aluminium hydride |
Sodium aluminum hydride hydrogen-storage grade | |
SodiuM aluMiniuM hydride, 2.0 M solution in THF, HySeal | |
SodiuM aluMiniuM hydride, 1.0 M solution in THF, HySeal | |
CAS | 13770-96-2 |
EINECS | 237-400-1 |
Chemical structure | |
Physico-chemical Properties | |
Molecular Formula | Na.AlH4 |
Molar Mass | 54 |
Density | 0.905g/mLat 25°C |
Melting Point | 178 °C |
Flash Point | -10 °C |
Storage Condition | water-free area |
Risk and Safety | |
Risk Codes | R14/15 -Reacts violently with water, liberating highly Flammable gases. |
R22 - Harmful if swallowed | |
R34 - Causes burns | |
R19 - May form explosive peroxides | |
R15 - Contact with water liberates extremely flammable gases | |
R11 - Highly Flammable | |
R40 - Limited evidence of a carcinogenic effect | |
R36/37/38 - Irritating to eyes, respiratory system and skin. | |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. | |
S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.) | |
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) | |
S7/8 -Keep container tightly closed and dry. | |
S33 - Take precautionary measures against static discharges. | |
S16 - Keep away from sources of ignition. | |
S36/37 - Wear suitable protective clothing and gloves. | |
UN IDs | UN 2835 4.3/PG 2 |
German Water Endangerment Class | 1 |
Registry of Toxic Effects of Chemical Substances | BD0180000 |
HS Code | 28500090 |
Hazard Class | 4.3 |
USE | sodium aluminum hydride is used as a hydrogen (or thermal) storage system. They have the advantages of large storage capacity and low cost. |
category | water burning articles |
toxicity grade | poisoning |
Acute toxicity | oral-mouse LD50: 740 mg/kg |
explosive hazard characteristics | explosion of hydrogen emitted by water and moist air |
flammability hazard characteristics | when water or moist air emits hydrogen |
storage and transportation characteristics | The warehouse is ventilated and dried at low temperature; It is stored separately from oxidant, halogen and strong acid |
extinguishing agent | dry powder, dry sand, dry powder |
Occupational Standard | TWA 2 mg (AL) /m3 |
Sodium aluminum hydride, chemical formula NaAlH4, is a typical aluminum hydride with significant activity and reaction rates. In view of its structural characteristics, safety must be strictly guaranteed during storage and transportation, and contact with air, water, etc., to prevent the risk of violent reactions.
In the field of scientific research, sodium aluminum hydride has attracted much attention because of its unique chemical properties. Its high Hydrogen storage density makes it an ideal hydrogen storage material. When hydrogen is needed to be released, sodium aluminum hydride can be hydrolyzed or pyrolyzed under specific conditions to release a large amount of hydrogen, thus showing a broad application prospect in the field of hydrogen energy.
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